Abstract:
Cu(NO
3)
2 was deposited into the nano-channels of mesoporous SBA-15 using the supercritical fluid deposition (SCFD) method at a pressure of about 20 MPa and a temperature of 50℃,where supercritical CO
2 was employed as the solvent and ethanol as the cosolvent. The subsequent reduction of this composite (Cu(NO
3)
2/SBA-15) led to copper nanowires and/or nanoparticles dispersed in the channels of SBA-15. The resultant Cu/SBA-15 composites were characterized by means of TEM and XRD. The results showed that Cu nanowires with the mean diameter 6 nm grow and curve along the channels of SBA-15 and their lengths vary from several nanometers to several micrometers;while the Cu nanoparticles with sizes of ~ 3 nm are highly dispersed in the channels. Moreover,it is found that with proper cosolvent,inorganic metallic can be solved in supercritical CO
2,and the morphology of copper can be controlled by changing the experimental conditions.